I've never seen a computer do this before upon loading the user account. Turns out the issue was the user account was corrupted. Just booted into safe mode and created a new user account and moved all of the data over to that account. Presto... problem solved.
I have but it was Malware related, really messed up the registry this was going back to before all these major bit encrypted malwares started to arise and as such a simple AV Boot disc scan removed it.
But those issues are annoying as you're never truly sure at first whether or not its Software or Hardware related.